Preservation of reverse osmosis membranes with non oxidizing biocides – comparison with SMBS
Sodium metabisulphite ( SMBS ) is the current standard preservation chemical used in RO plants during the shutdown. It is a cheap and efficient preservative, but its tendency to oxidize easily has several drawbacks. The use of a non-oxidizing biocide instead could solve some of the issues currently seen with the SMBS , but little has been reported about membrane compatibility and preservation efficiency in the long-term mode. Long-term membrane preservation trials have been executed with three different non-oxidizing biocides: DBNPA (2,2-dibromo-3-nitrilopropionamide), CMIT/MIT (5-chloro-2-methyl-4-isothiazolin-3-one (CMIT) and 2-methyl-4-isothiazolin-3-one (MIT), OIT (2-octyl-2H-isothiazol-3-one) as well as SMBS as the reference chemical. The suitability of these chemicals in this application was confirmed using both new Brackish Water Reverse Osmosis (BWRO) and used membranes with various membrane chemistries (Nanofiltration (NF), BWRO, Sea Water Reverse Osmosis (SWRO)) . The pres